Wake up and taste the water

Comets have made the news a number of times in recent months. These interplanetary travellers, which were once thought to herald doom, are now known to be among the most primitive objects in the solar system. And of course, comets periodically make visits from the far reaches of the solar system (regions known as the Oort Cloud and the Kuiper belt) to our more local neighbourhood.

Back in December, Comet ISON—the 'comet of the century'—made a much-watched and disappointing suicide plunge into the Sun. And just this week, the European Space Agency successfully 'woke up' its Rosetta spacecraft from its two-and-a-half-year hibernation.

Currently more than 400 million miles away from home, Rosetta is journeying towards the comet 67P/Churyumov-Gerasimenko. Once it arrives, it will first orbit, and then land on the comet's surface. Together, the orbiter and lander portions of the spacecraft are equipped with over 20 scientific instruments that will make important characterizations of the comet. Scientists working on the mission hope to find out if comets such as this, which contain complex organic molecules, may have played a role in seeding life on Earth.

Artist's impression of the European Space Agency's Rosetta spacecraft orbiting the comet 67P/Churyumov-Gerasimenko. Credit: ESA, C.Carreau / ATG medialab

There has also been a long-lived debate over whether or not comets contributed significantly to the delivery, early in its history, of Earth's vast water inventory.

Because water is such a vital ingredient for the sustenance of life here on Earth, we target our search for extraterrestrial life on places where water exists. Water therefore seems like a pretty obvious choice for an Earth-material to send as one of our interplanetary postcards. But how might an alien scientist be able to tell our Earth-water apart from any other foreign H₂O? We all know that water can vary drastically in its colour, salinity, taste, etc. So is there a characteristic signature of our water that portrays its Earthly provenance?

Earth: A water world. Credit: NASA

Lucky for us, chemistry has an answer. Hydrogen (H), like all elements is defined by the number of protons it contains. 'Normal' hydrogen contains just one proton in its nucleus. However, it is possible for a stable hydrogen atom to contain one or two neutrons in addition to the lone proton. The hydrogen isotope that has one proton and one neutron is known as deuterium (D). Heavy water is enriched in molecules that contain deuterium in place of the normal hydrogen.

Planetary scientists have shown that D/H ratios in water vary throughout the solar system. Measurements for a number of Oort Cloud comets reveal that they have D/H ratios which are more than twice the value for Earth's oceans, and are thus unlikely to have been the source of water on our planet.

Range of deuterium/hydrogen (D/H) ratios in solar system objects.
Credit: A. E. Saal et al. 2013, Science

Paul Hartogh and colleagues, however, showed in 2011 that a Jupiter-family comet (103P / Hartley 2), which probably originated from the Kuiper belt, has a D/H ratio that is much more consistent with that of Earth. This means that at least some of Earth's water may have been delivered by comets. Although in more recent work, Conel Alexander et al. argue that CI chondrites (the class of meteorite whose composition most closely resembles that of the Sun) were the principal source of terrestrial water.

And so the great water debate continues.  But no matter how, and from where, the water got here; get here it did. And we wouldn't be alive without it.